Crystal Lattice, Unit Cell and its content.

20/07/2020 Vinod 0 Comments

Crystal Lattice :-

If the three dimensional arrangement of constituent particles like atoms, molecules or ions in a crystal is represented diagrammatically, in which each particle is depicted as a point, the arrangement is called crystal lattice.

crystal lattices and unit cells
Fig. 1. Crystal Lattices.
  • Each point in a crystal lattice is called lattice point or lattice site. There are mainly three kinds of lattice points, that is, at the corners, at the face centres and within the unit cell.
  • In a Crystal lattice , lattice points are joined by straight lines to bring out the geometry of the lattice.
  • Bravais Lattices :-

In 1848, Auguste Bravais showed with the help of geometrical calculations that there are 14 possible three dimensional Crystal lattices, these are called Bravais lattices.

The 14 Bravais lattices The rhombohedral lattice R can be expressed either as a
Fig. 2. Unit Cells of 14 types of Bravais Lattices.

Crystal systems :-

It can be shown from geometrical considrations that theoratically, there can be 32 different combinations of elements of symmetry of a crystal. There are called 32 point groups or 32 systems. However, some of the systems have been grouped so that there are only 7 basic crystal systems, – cubic, tetragonal, orthorhombic, monoclinic, hexagonal, rhombohedral or trigonal or triclinic.

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Fig. 3. Table for edge length and angles of Crystal Systems.
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Fig. 4. Diagram of crystal systems ( seven types ).
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Fig. 5. Number of Bravais lattices in different Crystal systems.

Unit Cell :-

A unit cell is the smallest sample that represents the picture of the entire crystal lattice . A unit cell of a crystal possesses all the structural properties of the given crystal.

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Fig. 6. Crystal Lattice of Simple Unit Cell.

Its dimensions along the three edges :- a, b and c . These edges may or may not be mutually perpendicular.

Angles between the edges α, β and y · Thus, a unit cell is characterised by six parameters – a, b, c, α, β and y.

Types of Unit Cells :-

( a ) Primitive Unit Cells.

( b ) Centred Unit Cells.

Primitive Unit Cells :-

When constituent particles are present only on the corner positions of a unit cell, it is called primitive unit cell.

12 chem solidstate primitive
Fig. 7. Simple Unit Cell.

Centred Unit Cells :-

They are of three types :-

( 1 ) Body Centred Unit Cell :- If the particles are present at the centres of the cell in addition to the corners, then body centred unit is produced.

12 chem solidstate bodycentred
Fig. 8. Body Centred Unit Cell.

( 2 ) Face Centred Unit Cell :- If the particles are located at the centre of each face in addition to the corners, then face centred unit cell is produced.

12 chem solidstate facecentred
Fig. 9. Face Centred Unit Cell.

( 3 ) End face Centred Unit Cell :- If the particles are located at the centre of end face in addition to the corners, then end face centred unit is produced.

12 chem solidstate endcentered
Fig. 10. End Centred Unit Cell.

Unit Cell content ( Z ) :-

( 1 ) primitive or simple unit cell :- A simple cubic unit cell has eight atoms at eight corners and each atom is shared by eight unit cells.

Number of atoms in a simple cubic cell ( Z ) = no. of corner atom x contribution to one unit cell.

or Z = 8 x 1/8

or Z = 1

( 2 ) Body Centred Cubic unit cell :- It has eight atoms at eight corners and one atom at the body centre which is not shared by other cells.

Thus, for body centred cubic unit cell.

Z = 8 x 1/8 +1 = 2

( 3 ) Face Centred Cubic unit cell :- It has eight atoms at the eight corners and six atoms at the six faces. The corner atoms are shared by eight unit cells, while the atom at the face is shared by two unit cells.

Thus, for a face centred cubic unit cell,

Z = 8 x 1/8 + 6 x 1/2 = 4

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